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American physical chemist Willard Libby led a team of scientists in the post World War II era to develop a method that measures radiocarbon activity.

He is credited to be the first scientist to suggest that the unstable carbon isotope called radiocarbon or carbon 14 might exist in living matter. Libby and his team of scientists were able to publish a paper summarizing the first detection of radiocarbon in an organic sample. Libby who first measured radiocarbon’s rate of decay and established 5568 years ± 30 years as the half-life. Libby was awarded the Nobel Prize in Chemistry in recognition of his efforts to develop radiocarbon dating.1.

Accelerator mass spectrometry (AMS) is a modern radiocarbon dating method that is considered to be the more efficient way to measure radiocarbon content of a sample.

In this method, the carbon 14 content is directly measured relative to the carbon 12 and carbon 13 present. Some inorganic matter, like a shell’s aragonite component, can also be dated as long as the mineral’s formation involved assimilation of carbon 14 in equilibrium with the atmosphere.

Over the years, other secondary radiocarbon standards have been made.

Radiocarbon activity of materials in the background is also determined to remove its contribution from results obtained during a sample analysis.

The CRA conventions include (a) usage of the Libby half-life, (b) usage of Oxalic Acid I or II or any appropriate secondary standard as the modern radiocarbon standard, (c) correction for sample isotopic fractionation to a normalized or base value of -25.0 per mille relative to the ratio of carbon 12/carbon 13 in the carbonate standard VPDB – Cretaceous belemnite formation at Peedee in South Carolina, (d) zero BP (Before Present) is defined as AD 1950, and (e) the assumption that global radiocarbon levels are constant.It is rapidly oxidized in air to form carbon dioxide and enters the global carbon cycle.Plants and animals assimilate carbon 14 from carbon dioxide throughout their lifetimes.Background radiocarbon activity is measured, and the values obtained are deducted from the sample’s radiocarbon dating results.Background samples analyzed are usually geological in origin of infinite age such as coal, lignite, and limestone.

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